Molecular ions: a new addition to the quantum toolbox
Eric R. Hudson, UCLA
The low-energy internal structure of a diatomic molecule, e.g. the electric dipole
moment and vibrational, rotational, and Ω-doublet levels, presents a host of opportunities
for advances in quantum simulation, precision measurement, cold chemistry, and quantum
information. As such, the last decade has witnessed an enormous effort towards
producing ultracold molecules in well-defined rovibrational states [1]. Though this work has focused almost exclusively on neutral molecules, a sample of ultracold molecular ions
presents interesting possibilities as many of the goals of cold molecule physics can be
accomplished with molecular ions, but with the added benefit of a simple, reliable trapping.
We will discuss our implementation of a recent proposal for the production of
ultracold molecular ions [2], the experimental architecture’s applicability as a scalable
quantum computation platform [3,4], and the surprising results of a recent measurement of
chemistry between ultracold atoms and ions in the system [5].
1 R. V. Krems, W. C. Stwalley, and B. Friedrich, eds., Cold Molecules (CRC Press, 2009).
2 E.R. Hudson, “Method for the production of ultracold molecular ions”, Phys. Rev. A 79
032716(2010).
3 A. Andre et al., “A coherent all-electrical interface between polar molecules and
mesoscopic superconducting resonators“, Nature Phys. 2, 636 (2006).
4 D.I Schuster et al., “Cavity QED in a molecular ion trap”, Phys. Rev. A 83, 012311
(2011).
5 W.G. Rellergert et al., “Measurement of a Large Chemical Reaction Rate between
Ultracold Closed-Shell 40Ca Atoms and Open-Shell 174Yb Ions Held in a Hybrid
Atom-Ion Trap”, Phys. Rev. Lett. 107, 243201 (2011).